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Issue 87, 2013
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Coupling reaction of thioamides with sulfonyl azides: an efficient catalyst-free click-type ligation under mild conditions

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Abstract

We report a coupling reaction of thioamides and sulfonyl azides to generate sulfonyl amidines in the absence of any activation additives. The reaction progresses in various solvents under mild conditions. Water exhibits the highest performance with respect to efficiency.

Graphical abstract: Coupling reaction of thioamides with sulfonyl azides: an efficient catalyst-free click-type ligation under mild conditions

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Publication details

The article was received on 08 Aug 2013, accepted on 10 Sep 2013 and first published on 10 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC46055J
Citation: Chem. Commun., 2013,49, 10242-10244
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    Coupling reaction of thioamides with sulfonyl azides: an efficient catalyst-free click-type ligation under mild conditions

    M. Aswad, J. Chiba, T. Tomohiro and Y. Hatanaka, Chem. Commun., 2013, 49, 10242
    DOI: 10.1039/C3CC46055J

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