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Issue 89, 2013
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Quest for a highly connected robust porous metal–organic framework on the basis of a bifunctional linear linker and a rare heptanuclear zinc cluster

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Abstract

A strategy for building highly connected robust MOFs from linear ligands is exemplified by the construction of MTAF-4, a rare (6,9)-connected MOF, based on the custom-designed bifunctional linear ligand, 4-(1,2,3-triazol-4-yl)-benzoate, that connects two types of highly connected zinc cluster moieties generated in situ. MTAF-4 is robust and permanently microporous and is capable of adsorbing CO2, H2 and CH4 under high pressures.

Graphical abstract: Quest for a highly connected robust porous metal–organic framework on the basis of a bifunctional linear linker and a rare heptanuclear zinc cluster

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Publication details

The article was received on 05 Aug 2013, accepted on 17 Sep 2013 and first published on 18 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC45986A
Citation: Chem. Commun., 2013,49, 10516-10518
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    Quest for a highly connected robust porous metal–organic framework on the basis of a bifunctional linear linker and a rare heptanuclear zinc cluster

    W. Gao, R. Cai, L. Meng, L. Wojtas, W. Zhou, T. Yildirim, X. Shi and S. Ma, Chem. Commun., 2013, 49, 10516
    DOI: 10.1039/C3CC45986A

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