Issue 99, 2013
From the journal:

Chemical Communications

Synthesis of chiral metal oxide complexes with tunable electron transition-based optical activity†

Liguo Ma,a   Yingying Duan,a   Yuanyuan Cao,a   Shunsuke Asahina,b   Zheng Liuc  and  Shunai Che*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, P. R. China
E-mail: chesa@sjtu.edu.cn

b SMBU, JEOL, Akishima, Tokyo 196-8558, Japan

c Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Higashi 1-1-1, Tsukuba, Japan

Abstract

Chiral metal oxide complexes with tunable optical response to circularly polarised light over the full range of the UV-Vis absorption band were synthesised. This optical activity was attributed to electronic transitions from the ground state to the excited state or from the valence band to the conduction band under an asymmetric electric field.

Graphical abstract: Synthesis of chiral metal oxide complexes with tunable electron transition-based optical activity

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Article information

DOI
https://doi.org/10.1039/C3CC45960H
Article type
Communication
Submitted
05 Aug 2013
Accepted
18 Oct 2013
First published
21 Oct 2013

Chem. Commun., 2013,49, 11686-11688

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Synthesis of chiral metal oxide complexes with tunable electron transition-based optical activity

L. Ma, Y. Duan, Y. Cao, S. Asahina, Z. Liu and S. Che, Chem. Commun., 2013, 49, 11686 DOI: 10.1039/C3CC45960H

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