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Issue 92, 2013
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Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)–H bonds and aryl C(sp2)–H bonds

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Abstract

DTBP (di-tert-butyl peroxide) is utilized to mediate oxidative 1,2-difunctionalization of activated alkenes with an aryl C(sp2)–H bond and a benzylic C(sp3)–H bond for the synthesis of functionalized oxindoles. This reaction is a new organomediated strategy for alkene difunctionalization facilitated by Lewis acids.

Graphical abstract: Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)–H bonds and aryl C(sp2)–H bonds

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Publication details

The article was received on 31 Jul 2013, accepted on 30 Aug 2013 and first published on 30 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45861J
Citation: Chem. Commun., 2013,49, 10817-10819
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    Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)–H bonds and aryl C(sp2)–H bonds

    M. Zhou, C. Wang, R. Song, Y. Liu, W. Wei and J. Li, Chem. Commun., 2013, 49, 10817
    DOI: 10.1039/C3CC45861J

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