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Issue 87, 2013
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Introduction of hydrophilic groups onto the ortho-position of benzoate anions induced phase separation of the corresponding ionic liquids with water

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Abstract

Ionic liquids (ILs) composed of tetrabutylphosphonium cations and benzoate anion derivatives with hydrophilic hydroxyl or carboxyl groups introduced onto the ortho-position were found to be less hydrophilic and showed phase separation with water, whereas unmodified benzoate-type IL was freely miscible with water.

Graphical abstract: Introduction of hydrophilic groups onto the ortho-position of benzoate anions induced phase separation of the corresponding ionic liquids with water

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Publication details

The article was received on 25 Jul 2013, accepted on 10 Sep 2013 and first published on 10 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC45671D
Citation: Chem. Commun., 2013,49, 10248-10250
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    Introduction of hydrophilic groups onto the ortho-position of benzoate anions induced phase separation of the corresponding ionic liquids with water

    T. Ando, Y. Kohno, N. Nakamura and H. Ohno, Chem. Commun., 2013, 49, 10248
    DOI: 10.1039/C3CC45671D

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