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Issue 92, 2013
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Au144−xPdx(SR)60 nanomolecules

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Abstract

Au144−xPdx(SR)60 alloy nanomolecules were synthesized and characterized by ESI mass spectrometry to atomic precision. The number of Pd atoms can be varied by changing the incoming metal ratio and plateaus at 7 Pd atoms. Based on the proposed 3-shell structure of Au144(SR)60, we hypothesize that the Pd atoms are selectively incorporated into the central Au12 icosahedral core.

Graphical abstract: Au144−xPdx(SR)60 nanomolecules

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Publication details

The article was received on 25 Jul 2013, accepted on 12 Sep 2013 and first published on 14 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC45669B
Citation: Chem. Commun., 2013,49, 10850-10852
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    Au144−xPdx(SR)60 nanomolecules

    N. Kothalawala, C. Kumara, R. Ferrando and A. Dass, Chem. Commun., 2013, 49, 10850
    DOI: 10.1039/C3CC45669B

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