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Issue 80, 2013
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Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers

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Abstract

Self-assembly of CuX2 (X = ClO4 and BF4) with 2,3-bis(nicotinoyloxy)naphthalene yields a 1D loop-chain skeleton. The loop-chains form an ensemble constituting a unique 3D kagome-type structure with both hexagonal and trigonal supra-channels. The unprecedented supra-channel effects on the catalytic oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylbenzoquinone were investigated.

Graphical abstract: Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers

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Publication details

The article was received on 23 Jul 2013, accepted on 08 Aug 2013 and first published on 08 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45587D
Citation: Chem. Commun., 2013,49, 9182-9184
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    Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers

    H. Lee, T. H. Noh and O. Jung, Chem. Commun., 2013, 49, 9182
    DOI: 10.1039/C3CC45587D

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