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Issue 86, 2013
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Palladium-catalyzed insertion of α,β-unsaturated N-tosylhydrazones and trapping with carbon nucleophiles

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Abstract

Palladium-catalyzed carbene migratory insertion–cyclization reactions were reported, delivering dihydronaphthalene and indene derivatives in moderate to good yields. A three-component cross-coupling was also developed. The reactions are easy to handle, under mild conditions and various functional groups are tolerated.

Graphical abstract: Palladium-catalyzed insertion of α,β-unsaturated N-tosylhydrazones and trapping with carbon nucleophiles

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Publication details

The article was received on 23 Jul 2013, accepted on 27 Aug 2013 and first published on 28 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45583A
Citation: Chem. Commun., 2013,49, 10190-10192
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    Palladium-catalyzed insertion of α,β-unsaturated N-tosylhydrazones and trapping with carbon nucleophiles

    Y. Ye, P. Zhou, J. Luo, M. Zhong and Y. Liang, Chem. Commun., 2013, 49, 10190
    DOI: 10.1039/C3CC45583A

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