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Issue 81, 2013
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Non-enzymatic acylative kinetic resolution of primary allylic amines

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Abstract

A non-enzymatic acetyl transfer-based kinetic resolution of primary allylic amines is reported. The process involves the use of (1S,2S)-1 in conjunction with a supported ammonium salt and affords the corresponding enantio-enriched N-acetylated allylic amines with unprecedented levels of selectivity (s-factors up to 34).

Graphical abstract: Non-enzymatic acylative kinetic resolution of primary allylic amines

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Publication details

The article was received on 18 Jul 2013, accepted on 13 Aug 2013 and first published on 14 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45453C
Citation: Chem. Commun., 2013,49, 9338-9340
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    Non-enzymatic acylative kinetic resolution of primary allylic amines

    A. Kolleth, M. Cattoen, S. Arseniyadis and J. Cossy, Chem. Commun., 2013, 49, 9338
    DOI: 10.1039/C3CC45453C

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