Issue 80, 2013
From the journal:

Chemical Communications

Between red and yellow: evidence of intermediates in a vapochromic Pt(ii) salt†

Stephen D. Taylor,ab   Amie E. Norton,a   Robert T. Hart, Jr.,b   Mahmood K. Abdolmaleki,a   Jeanette A. Krausea  and  William B. Connick*a  

* Corresponding authors

a Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH 45221-0172, USA
E-mail: bill.connick@uc.edu
Fax: +1 513 556 9239
Tel: +1 513 556 0148

b The Shepherd Chemical Company, 4900 Beech St., Norwood, OH 45212, USA

Abstract

[Pt(tpy)Cl]ClO4·H2O (1·H2O) changes from red to yellow upon dehydration due to increased Pt⋯Pt distances. Spectroscopic, diffraction, gravimetric and calorimetric data demonstrate the presence of intermediates during hydration and dehydration which signifies surprising mechanistic complexity in the vapochromic response.

Graphical abstract: Between red and yellow: evidence of intermediates in a vapochromic Pt(ii) salt

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Article information

DOI
https://doi.org/10.1039/C3CC45418E
Article type
Communication
Submitted
17 Jul 2013
Accepted
15 Aug 2013
First published
15 Aug 2013

Chem. Commun., 2013,49, 9161-9163

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Between red and yellow: evidence of intermediates in a vapochromic Pt(II) salt

S. D. Taylor, A. E. Norton, R. T. Hart, M. K. Abdolmaleki, J. A. Krause and W. B. Connick, Chem. Commun., 2013, 49, 9161 DOI: 10.1039/C3CC45418E

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