Issue 83, 2013
From the journal:

Chemical Communications

Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids†

Kishor Padalaa  and  Masilamani Jeganmohan*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education and Research, Pune 411021, India
E-mail: mjeganmohan@iiserpune.ac.in

Abstract

Substituted acetanilides reacted with aromatic acids in the presence of [{RuCl2(p-cymene)}2], AgSbF6 and (NH4)2S2O8 in ClCH2CH2Cl at 100 °C for 24 h yielding ortho-benzoxylated acetanilides in good to excellent yields in a highly regioselective manner via C–H bond activation.

Graphical abstract: Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

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Article information

DOI
https://doi.org/10.1039/C3CC45350B
Article type
Communication
Submitted
15 Jul 2013
Accepted
22 Aug 2013
First published
22 Aug 2013

Chem. Commun., 2013,49, 9651-9653

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Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

K. Padala and M. Jeganmohan, Chem. Commun., 2013, 49, 9651 DOI: 10.1039/C3CC45350B

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