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Issue 78, 2013
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Catalytic enantioselective Amadori–Heyns rearrangement of racemic α-hydroxy ketones with arylamines: synthesis of optically active α-arylamino ketones

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Abstract

A novel synthesis of optically active α-arylamino ketones through an organocatalytic enantioselective Amadori–Heyns rearrangement is described.

Graphical abstract: Catalytic enantioselective Amadori–Heyns rearrangement of racemic α-hydroxy ketones with arylamines: synthesis of optically active α-arylamino ketones

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Publication details

The article was received on 12 Jul 2013, accepted on 31 Jul 2013, published on 31 Jul 2013 and first published online on 31 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC45278F
Citation: Chem. Commun., 2013,49, 8812-8814
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    Catalytic enantioselective Amadori–Heyns rearrangement of racemic α-hydroxy ketones with arylamines: synthesis of optically active α-arylamino ketones

    A. Frongia, F. Secci, F. Capitta, P. P. Piras and M. L. Sanna, Chem. Commun., 2013, 49, 8812
    DOI: 10.1039/C3CC45278F

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