Indium@silica core–shell nanoparticles as plasmonic enhancers of molecular luminescence in the UV region

François Magnan; Joanie Gagnon; Frédéric-Georges Fontaine; Denis Boudreau

doi:10.1039/C3CC45276J

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Chemical Communications

Issue 81, 2013

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Indium@silica core–shell nanoparticles as plasmonic enhancers of molecular luminescence in the UV region

François Magnan,^a^b Joanie Gagnon,^a Frédéric-Georges Fontaine^b and Denis Boudreau*^a

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Département de Chimie et Centre d'optique, photonique et laser (COPL), Université Laval, Québec, Canada
E-mail: denis.boudreau@chm.ulaval.ca;
Fax: +1 418-656-7916 ;
Tel: +1 418-656-3287

Département de Chimie et Centre de recherche sur la catalyse et la chimie verte (C3V), Université Laval, Québec, Canada

Chem. Commun., 2013,49, 9299-9301

DOI: 10.1039/C3CC45276J
Received 12 Jul 2013, Accepted 13 Aug 2013
First published online 14 Aug 2013

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Large fluorescence enhancement of UV-active molecular models Carbostyril 124 and tryptophan by core–shell indium-based plasmonic architectures demonstrates the metal's potential in the design of bioprobes. Precise control over the metal–fluorophore distance is achieved through the controlled deposition of a uniform silica layer over the nanosized indium particles.