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Issue 40, 2014
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Copper-catalyzed free-radical C–H arylation of pyrroles

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Abstract

A room temperature copper-catalyzed radical arylation of pyrroles with anilines, through in situ generated aryl diazonium salts, has been developed under neutral conditions. Experimental and theoretical studies explain the crucial role of CaCO3 and the high regioselectivity observed.

Graphical abstract: Copper-catalyzed free-radical C–H arylation of pyrroles

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Publication details

The article was received on 11 Jul 2013, accepted on 05 Aug 2013 and first published on 07 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45240A
Citation: Chem. Commun., 2014,50, 5236-5238
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    Copper-catalyzed free-radical C–H arylation of pyrroles

    A. Honraedt, M. Raux, E. L. Grognec, D. Jacquemin and F. Felpin, Chem. Commun., 2014, 50, 5236
    DOI: 10.1039/C3CC45240A

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