Jump to main content
Jump to site search

Issue 80, 2013
Previous Article Next Article

Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes

Author affiliations

Abstract

We report a stereoselective route to synthesize (E)-2-bromo-2-fluoro-1-(2,4,6-tri-t-butylphenyl)-2-phosphaethene. Configurationally and conformationally controlled 2-fluoro-1-phosphaethene [Mes*P[double bond, length as m-dash]C(F)H; Mes* = 2,4,6-tBu3C6H2] and 2-fluoro-1,3-diphosphapropene [Mes*P[double bond, length as m-dash]C(F)-PPh2] were synthesized and the NMR data, including relaxation parameters, were collected.

Graphical abstract: Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 Jul 2013, accepted on 08 Aug 2013 and first published on 08 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45237A
Citation: Chem. Commun., 2013,49, 9221-9223
  •   Request permissions

    Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes

    S. Ito, T. Nakagawa and K. Mikami, Chem. Commun., 2013, 49, 9221
    DOI: 10.1039/C3CC45237A

Search articles by author

Spotlight

Advertisements