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Issue 2, 2014
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Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

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Abstract

Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses.

Graphical abstract: Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

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Publication details

The article was received on 08 Jul 2013, accepted on 30 Jul 2013, published on 31 Jul 2013 and first published online on 31 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC45134H
Citation: Chem. Commun., 2014,50, 162-164
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    Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

    R. R. Rodrigues, C. L. Dorsey, C. A. Arceneaux and T. W. Hudnall, Chem. Commun., 2014, 50, 162
    DOI: 10.1039/C3CC45134H

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