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Issue 78, 2013
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A Pd–diimine catalytic inimer for synthesis of polyethylenes of hyperbranched-on-hyperbranched and star architectures

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Abstract

A Pd–diimine catalytic inimer containing uniquely catalytic, initiating, and monomeric functionalities in one catalyst molecule is designed. It enables the first self-condensing vinyl copolymerization of ethylene, leading to polyethylenes of a hyperbranched-on-hyperbranched architecture. Meanwhile, it also facilitates the synthesis of star polyethylenes by tandem UV-coordinative polymerization.

Graphical abstract: A Pd–diimine catalytic inimer for synthesis of polyethylenes of hyperbranched-on-hyperbranched and star architectures

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Publication details

The article was received on 07 Jul 2013, accepted on 31 Jul 2013 and first published on 01 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45101A
Citation: Chem. Commun., 2013,49, 8800-8802
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    A Pd–diimine catalytic inimer for synthesis of polyethylenes of hyperbranched-on-hyperbranched and star architectures

    L. Xu and Z. Ye, Chem. Commun., 2013, 49, 8800
    DOI: 10.1039/C3CC45101A

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