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Issue 83, 2013
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Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst

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Abstract

Consecutive intramolecular desymmetrization and kinetic resolution of 2-substituted N-phenoxycarbonylserinols have been achieved in one-pot by a single chiral catalyst, bisox(7)–CuCl2, to form oxazolidinones with remarkable enantioselectivities (94–99% ee) as tert-alkylamine building blocks. The process culminates in a dual-function of the chiral catalyst.

Graphical abstract: Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst

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Publication details

The article was received on 07 Jul 2013, accepted on 22 Aug 2013 and first published on 10 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC45099F
Citation: Chem. Commun., 2013,49, 9669-9671
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    Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst

    Y. S. You, T. W. Kim and S. H. Kang, Chem. Commun., 2013, 49, 9669
    DOI: 10.1039/C3CC45099F

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