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Issue 81, 2013
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[Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties

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Abstract

Ambient temperature solid-state reaction of Pb(OAc)2 with TabHPF6 afforded an intermediate product [Pb(Tab)2]2(PF6)4, which further reacted with 4,4′-bipy in the solid state to generate a unique 2D cationic coordination polymer [Pb(Tab)2(4,4′-bipy)](PF6)2 in quantitative yield. Both complexes possess a low dielectric constant and low dielectric loss in the high electric field frequency range.

Graphical abstract: [Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties

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Publication details

The article was received on 05 Jul 2013, accepted on 27 Jul 2013 and first published on 30 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC45066J
Citation: Chem. Commun., 2013,49, 9248-9250
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    [Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties

    F. Wang, C. Ni, Q. Liu, F. Li, J. Shi, H. Li and J. Lang, Chem. Commun., 2013, 49, 9248
    DOI: 10.1039/C3CC45066J

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