Issue 84, 2013
From the journal:

Chemical Communications

Pd-Catalyzed stereospecific allyl–aryl coupling of allylic alcohols with arylboronic acids†

Jiang Ye,a   Jingming Zhao,a   Jing Xu,a   Yuxue Maoa  and  Yong Jian Zhang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, and Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China
E-mail: yjian@sjtu.edu.cn
Fax: +86 21 5474 1297
Tel: +86 21 5474 0787

Abstract

An efficient method for Pd-catalyzed stereospecific allyl–aryl coupling of allylic alcohols with arylboronic acids has been described. The reactions proceeded smoothly in the presence of Pd2(dba)3·CHCl3 and racemic BINAP under mild and neutral conditions, affording allyl–aryl coupling products in moderate to high yields with excellent stereospecificities.

Graphical abstract: Pd-Catalyzed stereospecific allyl–aryl coupling of allylic alcohols with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/C3CC45053H
Article type
Communication
Submitted
05 Jul 2013
Accepted
20 Aug 2013
First published
21 Aug 2013

Chem. Commun., 2013,49, 9761-9763

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Pd-Catalyzed stereospecific allyl–aryl coupling of allylic alcohols with arylboronic acids

J. Ye, J. Zhao, J. Xu, Y. Mao and Y. J. Zhang, Chem. Commun., 2013, 49, 9761 DOI: 10.1039/C3CC45053H

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