The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka, Ibaraki-shi, Osaka 567-0047, Japan
E-mail: firstname.lastname@example.org; Fax: +81-6-6879-8469
; Tel: +81-6-6879-8465
Chem. Commun., 2013,49, 11224-11226
26 Jun 2013,
09 Oct 2013
First published online
14 Oct 2013
Novel enantioselective catalysis involving a Pd(II)–Pd(IV) cycle was developed by utilizing a SPRIX ligand. Treatment of alkenyl alcohols with a catalytic amount of Pd–SPRIX and TfOH in the presence of PhI(OAc)2 gave optically active 3-oxy-tetrahydrofuran derivatives in good yields.
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