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Issue 78, 2013
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Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

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Abstract

A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.

Graphical abstract: Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

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Publication details

The article was received on 26 Jun 2013, accepted on 30 Jul 2013 and first published on 31 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44787A
Citation: Chem. Commun., 2013,49, 8830-8832
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    Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

    L. Zhang, S. Yang, X. Huang, J. You and F. Song, Chem. Commun., 2013, 49, 8830
    DOI: 10.1039/C3CC44787A

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