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Issue 81, 2013
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Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

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Abstract

The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.

Graphical abstract: Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

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Publication details

The article was received on 18 Jun 2013, accepted on 12 Aug 2013 and first published on 13 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC44558E
Citation: Chem. Commun., 2013,49, 9296-9298
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    Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

    K. Yamanishi, T. Yairi, K. Suzuki and M. Kondo, Chem. Commun., 2013, 49, 9296
    DOI: 10.1039/C3CC44558E

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