Issue 81, 2013
From the journal:

Chemical Communications

Biomimic O2activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions†

Katsunori Yamanishi,a   Takeshi Yairi,b   Keisuke Suzukib  and  Mitsuru Kondo*abc  

* Corresponding authors

a Graduate School of Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan

b Department of Chemistry, Faculty of Science, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan

c Green Chemistry Research Division, Research Institute of Green Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan
E-mail: scmkond@ipc.shizuoka.ac.jp

Abstract

The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.

Graphical abstract: Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

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Article information

DOI
https://doi.org/10.1039/C3CC44558E
Article type
Communication
Submitted
18 Jun 2013
Accepted
12 Aug 2013
First published
13 Aug 2013

Chem. Commun., 2013,49, 9296-9298

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Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

K. Yamanishi, T. Yairi, K. Suzuki and M. Kondo, Chem. Commun., 2013, 49, 9296 DOI: 10.1039/C3CC44558E

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