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Issue 73, 2013
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Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a ‘bottle around the ship’ approach

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Abstract

An enantioselective catalyst, consisting of a chiral Mn(III)salen complex entrapped in the MIL-101 metal organic framework, is reported. For the first time, we assemble a robust MOF-cage around a chiral complex. The heterogeneous catalyst shows the same selectivity as the homogeneous complex and is fully recyclable. Theoretical calculations provide insight into this retention of selectivity.

Graphical abstract: Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a ‘bottle around the ship’ approach

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Publication details

The article was received on 14 Jun 2013, accepted on 11 Jul 2013 and first published on 12 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44473B
Citation: Chem. Commun., 2013,49, 8021-8023
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    Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a ‘bottle around the ship’ approach

    T. Bogaerts, A. Van Yperen-De Deyne, Y. Liu, F. Lynen, V. Van Speybroeck and P. Van Der Voort, Chem. Commun., 2013, 49, 8021
    DOI: 10.1039/C3CC44473B

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