Jump to main content
Jump to site search

Issue 71, 2013
Previous Article Next Article

Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides

Author affiliations

Abstract

Reactions of propargylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) have been found to give the corresponding trifluoromethylated products in good to high yields with a high selectivity.

Graphical abstract: Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Jun 2013, accepted on 03 Jul 2013 and first published on 04 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44434A
Citation: Chem. Commun., 2013,49, 7809-7811
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides

    Y. Miyake, S. Ota, M. Shibata, K. Nakajima and Y. Nishibayashi, Chem. Commun., 2013, 49, 7809
    DOI: 10.1039/C3CC44434A

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements