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Issue 75, 2013
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Unprecedented infinite lanthanide hydroxide ribbons [Ln33-OH)3]n6n+ in a 3-D metal–organic framework

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Abstract

Unprecedented infinite lanthanide hydroxide ribbons interconnected by Pra2biim2− (H2Pra2biim = 1′-di(propionic acid)-2,2′-biimidazole) into 3-D [Ln33-OH)3(Pra2biim)3 (H2O)2]n·4nH2O (Ln = Nd, Pr and La) have been achieved by utilizing the unique H2Pra2biim–Ln3+ hydrolysis system. The Ln⋯Ln antiferromagnetic coupling with magnetic anisotropy has been observed.

Graphical abstract: Unprecedented infinite lanthanide hydroxide ribbons [Ln3(μ3-OH)3]n6n+ in a 3-D metal–organic framework

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Publication details

The article was received on 04 Jun 2013, accepted on 18 Jul 2013 and first published on 18 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44181D
Citation: Chem. Commun., 2013,49, 8344-8346
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    Unprecedented infinite lanthanide hydroxide ribbons [Ln33-OH)3]n6n+ in a 3-D metal–organic framework

    R. Sang and L. Xu, Chem. Commun., 2013, 49, 8344
    DOI: 10.1039/C3CC44181D

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