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Issue 68, 2013
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B–H activation and H–H formation: two consecutive heterolytic processes on an osmium–hydrogensulfide bond

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Abstract

Heterolytic B–H activation and H–H formation on an Os–SH bond give borylthiolate-dihydrogen derivatives. These species exchange borylthiol by borane to afford σ-borane derivatives or release H2 and undergo a hydride-boryl exchange to yield boryl-hydrogensulfide complexes depending on the boryl group bonded to the sulfur atom.

Graphical abstract: B–H activation and H–H formation: two consecutive heterolytic processes on an osmium–hydrogensulfide bond

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Publication details

The article was received on 31 May 2013, accepted on 27 Jun 2013 and first published on 28 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC44102D
Citation: Chem. Commun., 2013,49, 7543-7545
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    B–H activation and H–H formation: two consecutive heterolytic processes on an osmium–hydrogensulfide bond

    M. A. Esteruelas, A. M. López, M. Mora and E. Oñate, Chem. Commun., 2013, 49, 7543
    DOI: 10.1039/C3CC44102D

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