Issue 68, 2013

B–H activation and H–H formation: two consecutive heterolytic processes on an osmium–hydrogensulfide bond

Abstract

Heterolytic B–H activation and H–H formation on an Os–SH bond give borylthiolate-dihydrogen derivatives. These species exchange borylthiol by borane to afford σ-borane derivatives or release H2 and undergo a hydride-boryl exchange to yield boryl-hydrogensulfide complexes depending on the boryl group bonded to the sulfur atom.

Graphical abstract: B–H activation and H–H formation: two consecutive heterolytic processes on an osmium–hydrogensulfide bond

Supplementary files

Article information

Article type
Communication
Submitted
31 May 2013
Accepted
27 Jun 2013
First published
28 Jun 2013

Chem. Commun., 2013,49, 7543-7545

B–H activation and H–H formation: two consecutive heterolytic processes on an osmium–hydrogensulfide bond

M. A. Esteruelas, A. M. López, M. Mora and E. Oñate, Chem. Commun., 2013, 49, 7543 DOI: 10.1039/C3CC44102D

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