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Issue 76, 2013
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Metal ion directed metal–organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

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Abstract

Three novel self-catenated 4-connected uninodal (65·8)-mok metal–organic rotaxane frameworks (MORFs) containing cucurbit[6]uril were constructed from the in situ trans/cis-configuration (1 : 1) of rotaxanes by taking advantage of a d10 metal ion directed synthesis. It was revealed that the effect of hydrogen bonds and π–π stacking interactions play significant roles in the self-assembly process.

Graphical abstract: Metal ion directed metal–organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

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Publication details

The article was received on 27 May 2013, accepted on 30 Jul 2013 and first published on 31 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43990A
Citation: Chem. Commun., 2013,49, 8555-8557
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    Metal ion directed metal–organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

    J. Liang, X. Wang, Y. Jiao, C. Qin, K. Shao, Z. Su and Q. Wu, Chem. Commun., 2013, 49, 8555
    DOI: 10.1039/C3CC43990A

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