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Issue 88, 2013
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Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine

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Abstract

Organosilanes bearing a phosphine imide moiety were synthesized and crystallographically characterized. Reaction of the pentacoordinated hydrodiphenylsilyl derivative with water gave [2-(diphenylphosphino)phenyl]diphenylsilanol accompanied by both reduction of the phosphine imide moiety and hydrolytic oxidation of the Si–H moiety.

Graphical abstract: Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine

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Publication details

The article was received on 26 May 2013, accepted on 13 Jun 2013 and first published on 28 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43955K
Citation: Chem. Commun., 2013,49, 10373-10375
  • Open access: Creative Commons BY license
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    Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine

    N. Kano, K. Yanaizumi, X. Meng, N. Havare and T. Kawashima, Chem. Commun., 2013, 49, 10373
    DOI: 10.1039/C3CC43955K

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