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Issue 66, 2013
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Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl group

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Abstract

Iron-catalyzed trifluoromethylation with concomitant 1,2-migration of an aryl group starting from diaryl allyl alcohol was achieved under mild conditions. This reaction system affords α-substituted-β-trifluoromethyl carbonyl compounds in high efficiency. In the case of substrates bearing different aryl groups, selective migration was observed.

Graphical abstract: Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl group

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Publication details

The article was received on 25 May 2013, accepted on 16 Jun 2013, published on 17 Jun 2013 and first published online on 17 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43936D
Citation: Chem. Commun., 2013,49, 7346-7348
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    Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl group

    H. Egami, R. Shimizu, Y. Usui and M. Sodeoka, Chem. Commun., 2013, 49, 7346
    DOI: 10.1039/C3CC43936D

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