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Issue 72, 2013
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Facile synthesis of heterotrimetallic metal–string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

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Abstract

This communication provides a practical strategy for the synthesis of heterotrimetallic extended metal atom chains with supported dpa ligands. The transformation of the CoCoRh to a NiCoRh trinuclear complex can be achieved by direct metallic replacement. Furthermore, the first (CoRh)4+ metal–metal bond is described here.

Graphical abstract: Facile synthesis of heterotrimetallic metal–string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

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Publication details

The article was received on 24 May 2013, accepted on 09 Jul 2013 and first published on 30 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43909G
Citation: Chem. Commun., 2013,49, 7938-7940
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    Facile synthesis of heterotrimetallic metal–string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

    M. Cheng, C. Mai, C. Yeh, G. Lee and S. Peng, Chem. Commun., 2013, 49, 7938
    DOI: 10.1039/C3CC43909G

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