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Issue 70, 2013
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Two homochiral organocatalytic metal organic materials with nanoscopic channels

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Abstract

Two homochiral organocatalytic MOMs were prepared using tetra- and octa-carboxylate ligands, respectively. The nanoscopic channels in these MOMs are lined by organonocatalytic chiral phosphoric acid derivatives of binol and ocMOM-1 exhibited improved enantioselectivity over the parent ligand in the context of transfer hydrogenation of a series of benzoxazines.

Graphical abstract: Two homochiral organocatalytic metal organic materials with nanoscopic channels

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Publication details

The article was received on 20 May 2013, accepted on 12 Jul 2013 and first published on 12 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43801E
Citation: Chem. Commun., 2013,49, 7693-7695
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    Two homochiral organocatalytic metal organic materials with nanoscopic channels

    Z. Zhang, Y. R. Ji, L. Wojtas, W. Gao, S. Ma, M. J. Zaworotko and J. C. Antilla, Chem. Commun., 2013, 49, 7693
    DOI: 10.1039/C3CC43801E

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