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Issue 70, 2013
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Nickel-catalyzed manipulation of tertiary phosphines via highly selective C–P bond cleavage

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Abstract

A catalytic cycle involving oxidative addition of nickel(0) with a carbon–carbon single bond in the three-membered ring of diarylmethylenecyclopropa[b]naphthalenes, highly selective cleavage of the C–P bond, and migration of the aryl group of phosphine consequently provides a new type of bulky phosphine in excellent yields.

Graphical abstract: Nickel-catalyzed manipulation of tertiary phosphines via highly selective C–P bond cleavage

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Publication details

The article was received on 15 May 2013, accepted on 01 Jul 2013 and first published on 02 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43640C
Citation: Chem. Commun., 2013,49, 7747-7749
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    Nickel-catalyzed manipulation of tertiary phosphines via highly selective C–P bond cleavage

    J. Cao, X. Huang and L. Wu, Chem. Commun., 2013, 49, 7747
    DOI: 10.1039/C3CC43640C

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