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Issue 56, 2013
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Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

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Abstract

Two salts of [FeL2]2+ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.

Graphical abstract: Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

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Publication details

The article was received on 14 May 2013, accepted on 29 May 2013 and first published on 30 May 2013


Article type: Communication
DOI: 10.1039/C3CC43613F
Citation: Chem. Commun., 2013,49, 6280-6282
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    Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

    T. D. Roberts, M. A. Little, F. Tuna, C. A. Kilner and M. A. Halcrow, Chem. Commun., 2013, 49, 6280
    DOI: 10.1039/C3CC43613F

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