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Issue 65, 2013
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Planar tris-N-heterocyclic carbenes

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Abstract

To further explore the coordination chemistry of poly-carbene complexes, two triphenylene-based planar tridentate N-heterocyclic carbenes and their corresponding tri-gold complexes were synthesized. Molecular structures of the tert-butyl substituted tritopic free carbene and the tri-nuclear gold complex were determined experimentally. A silver-dicarbene organometallic polymer was also prepared with the newly synthesized tris-NHC.

Graphical abstract: Planar tris-N-heterocyclic carbenes

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Publication details

The article was received on 03 May 2013, accepted on 17 Jun 2013 and first published on 18 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43278E
Citation: Chem. Commun., 2013,49, 7258-7260
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    Planar tris-N-heterocyclic carbenes

    Y. Wang, M. Chang, G. Lee, S. Peng and C. Chiu, Chem. Commun., 2013, 49, 7258
    DOI: 10.1039/C3CC43278E

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