Jump to main content
Jump to site search

Issue 56, 2013
Previous Article Next Article

Ferromagnetic superexchange in a 1D –[LaIII–radical]– coordination polymer

Author affiliations

Abstract

The first coordination polymer of a bridging radical 1,2,3,5-dithiadiazolyl ligand is reported. Upon coordination with the La(hfac)3 fragment, the paramagnetic 4-(benzoxazol-2′-yl)-1,2,3,5-dithiadiazolyl (boaDTDA) ligand forms a one-dimensional (1D) alternating –[La(hfac)3–boaDTDA]npolymer exhibiting ferromagnetic (FM) coupling between the radicals, mediated through the diamagnetic LaIII ion (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato).

Graphical abstract: Ferromagnetic superexchange in a 1D –[LaIII–radical]– coordination polymer

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 02 May 2013, accepted on 24 May 2013 and first published on 28 May 2013


Article type: Communication
DOI: 10.1039/C3CC43267J
Citation: Chem. Commun., 2013,49, 6271-6273
  •   Request permissions

    Ferromagnetic superexchange in a 1D –[LaIII–radical]– coordination polymer

    E. M. Fatila, R. Clérac, M. Rouzières, D. V. Soldatov, M. Jennings and K. E. Preuss, Chem. Commun., 2013, 49, 6271
    DOI: 10.1039/C3CC43267J

Search articles by author