UPMC Uni Paris 06, Collège de France and CNRS, UMR 7574, Laboratoire de Chimie de la Matière Condensée, case 196, 4 place Jussieu, 75252 Paris Cedex 05, France
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Chem. Commun., 2013,49, 7403-7405
26 Apr 2013,
18 Jun 2013
First published online
19 Jun 2013
Structural changes in a porous hybrid inorganic–organic ZIF-8 compound have been explored using hyperpolarized 129Xe NMR of adsorbed xenon at various temperatures. Upon xenon adsorption at low temperature, the organic linkers undergo a reorientation leading to a stepwise increase in xenon adsorption and in chemical shift.
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