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Issue 68, 2013
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Stabilization and strong oxidizing properties of Ag(II) in a fluorine-free solvent

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Abstract

Divalent silver is stabilized in concentrated sulphuric acid and oleums. The formal redox potential of the Ag(II)/Ag(I) redox pair is markedly dependent on the Hammett acidity function and it reaches +2.90 V vs. NHE in 33% oleum thus rivalling E° for the F2/2F redox pair (+2.87 V).

Graphical abstract: Stabilization and strong oxidizing properties of Ag(ii) in a fluorine-free solvent

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Publication details

The article was received on 25 Apr 2013, accepted on 04 Jun 2013 and first published on 20 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43072C
Citation: Chem. Commun., 2013,49, 7480-7482
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    Stabilization and strong oxidizing properties of Ag(II) in a fluorine-free solvent

    P. Połczyński, R. Jurczakowski and W. Grochala, Chem. Commun., 2013, 49, 7480
    DOI: 10.1039/C3CC43072C

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