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Issue 73, 2013
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One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition

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Abstract

A series of poly(3-hexylthiophene)-b-poly(hexadecyloxylallene) copolymers has been synthesized in one pot via sequential monomer addition by using Ni(dppp)Cl2 as a single catalyst. The copolymerization has been revealed to proceed by a controlled chain extension mechanism and the block copolymer can self-assemble into a well-defined supramolecular structure in solution and exhibit microphase separation in the solid state.

Graphical abstract: One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition

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Publication details

The article was received on 24 Apr 2013, accepted on 12 Jul 2013 and first published on 12 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43026J
Citation: Chem. Commun., 2013,49, 8069-8071
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    One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition

    Z. Wu, Y. Chen, Y. Wang, X. He, Y. Ding and N. Liu, Chem. Commun., 2013, 49, 8069
    DOI: 10.1039/C3CC43026J

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