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Issue 53, 2013
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Gold(I) triazolyls: organometallic synthesis in air and aqueous media

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Abstract

(N-heterocyclic carbene)gold(I) alkynyls and organic azides have undergone cycloadditions in watert-butanol mixtures with copper metal as the pre-catalyst to give new gold(I) triazolyls in high purity. Substrate tolerability was outlined for organoazides bearing a range of functional groups, and branching alpha to the azide moiety. All products are validated by combustion analysis or high-resolution mass spectrometry; two are also confirmed crystallographically.

Graphical abstract: Gold(i) triazolyls: organometallic synthesis in air and aqueous media

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Publication details

The article was received on 23 Apr 2013, accepted on 17 May 2013 and first published on 22 May 2013


Article type: Communication
DOI: 10.1039/C3CC43016B
Citation: Chem. Commun., 2013,49, 5990-5992
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    Gold(I) triazolyls: organometallic synthesis in air and aqueous media

    J. E. Heckler, N. Deligonul, A. L. Rheingold and T. G. Gray, Chem. Commun., 2013, 49, 5990
    DOI: 10.1039/C3CC43016B

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