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Issue 65, 2013
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Engineering robust polar chiral clathrate crystals

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Abstract

The R-(+)-enantiomeric form of Dianin's compound and the S-(+)-enantiomeric form of its direct thiachroman analogue both obtained chromatographically employing a cellulose tris(3,5-dimethylphenylcarbamate) column, are shown to undergo supramolecular assembly to form a polar clathrate lattice which is stable even in the absence of a consolidating guest component.

Graphical abstract: Engineering robust polar chiral clathrate crystals

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Publication details

The article was received on 23 Apr 2013, accepted on 14 Jun 2013 and first published on 17 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43012J
Citation: Chem. Commun., 2013,49, 7198-7200
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    Engineering robust polar chiral clathrate crystals

    C. S. Frampton, K. A. Ketuly, A. H. A. Hadi, J. H. Gall and D. D. MacNicol, Chem. Commun., 2013, 49, 7198
    DOI: 10.1039/C3CC43012J

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