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Issue 70, 2013
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Polymer nitrile N-oxides directed toward catalyst- and solvent-free click grafting

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Abstract

A general method for the one-pot synthesis of stable polymer nitrile N-oxides was developed by a combination of 1,1-diphenylnitroethene with a living anionic polymer. The polymer nitrile N-oxide served as a facile and effective grafting tool for use with polymers containing unsaturated bonds in a catalyst-free and solvent-free [2+3] cycloaddition.

Graphical abstract: Polymer nitrile N-oxides directed toward catalyst- and solvent-free click grafting

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Publication details

The article was received on 23 Apr 2013, accepted on 03 Jul 2013 and first published on 04 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC42992J
Citation: Chem. Commun., 2013,49, 7723-7725
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    Polymer nitrile N-oxides directed toward catalyst- and solvent-free click grafting

    C. Wang, Y. Koyama, M. Yonekawa, S. Uchida and T. Takata, Chem. Commun., 2013, 49, 7723
    DOI: 10.1039/C3CC42992J

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