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Issue 56, 2013
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Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

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Abstract

Iron complexes derived from 6-diaminotriazyl-2,2′-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.

Graphical abstract: Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

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Publication details

The article was received on 17 Apr 2013, accepted on 30 May 2013 and first published on 31 May 2013


Article type: Communication
DOI: 10.1039/C3CC42851F
Citation: Chem. Commun., 2013,49, 6331-6333
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    Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

    M. C. Young, E. Liew, J. Ashby, K. E. McCoy and R. J. Hooley, Chem. Commun., 2013, 49, 6331
    DOI: 10.1039/C3CC42851F

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