Issue 56, 2013
From the journal:

Chemical Communications

Influence of C–H⋯π interactions on the solid-state [2+2] cycloaddition reaction of a Ag(i) coordination complex in an inorganic co-crystal†

Goutam Kumar Kole,a   Raghavender Medishetty,a   Lip Lin Koha  and  Jagadese J. Vittal*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, Singapore 117543
E-mail: chmjjv@nus.edu.sg
Fax: +65 67791691
Tel: +65 6516 2975

Abstract

The C–H⋯π interaction plays a vital role in directing a single-crystal to single-crystal [2+2] cycloaddition reaction to form an intramolecular head-to-head photodimer compared to an intermolecular head-to-tail photoproduct of 4-styrylpyridine of a Ag(I) coordination complex in an inorganic co-crystal.

Graphical abstract: Influence of C–H⋯π interactions on the solid-state [2+2] cycloaddition reaction of a Ag(i) coordination complex in an inorganic co-crystal

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Article information

DOI
https://doi.org/10.1039/C3CC42793E
Article type
Communication
Submitted
16 Apr 2013
Accepted
16 May 2013
First published
16 May 2013

Chem. Commun., 2013,49, 6298-6300

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Influence of C–H⋯π interactions on the solid-state [2+2] cycloaddition reaction of a Ag(I) coordination complex in an inorganic co-crystal

G. K. Kole, R. Medishetty, L. L. Koh and J. J. Vittal, Chem. Commun., 2013, 49, 6298 DOI: 10.1039/C3CC42793E

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