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Issue 65, 2013
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Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

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Abstract

Hydroalkoxymethylation of electron-deficient alkenes using alkoxymethyltrifluoroborates by photoredox catalysis has been developed. Highly reactive alkoxymethyl radicals can be easily generated from oxidation of alkoxymethyltrifluoroborates via a visible-light-induced SET process.

Graphical abstract: Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

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Publication details

The article was received on 12 Apr 2013, accepted on 18 Jun 2013 and first published on 19 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC42695E
Citation: Chem. Commun., 2013,49, 7249-7251
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    Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

    K. Miyazawa, Y. Yasu, T. Koike and M. Akita, Chem. Commun., 2013, 49, 7249
    DOI: 10.1039/C3CC42695E

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