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Issue 54, 2013
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Organocatalytic asymmetric desymmetrization: efficient construction of spirocyclic oxindoles bearing a unique all-carbon quaternary stereogenic center via sulfa-Michael addition

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Abstract

An unprecedented enantioselective desymmetrization of spiro cyclohexadienone oxindoles has been developed successfully via organocatalyzed asymmetric SMA, which provides facile access to spirocyclic oxindoles bearing a unique all-carbon quaternary stereogenic center with excellent levels of stereoselectivity.

Graphical abstract: Organocatalytic asymmetric desymmetrization: efficient construction of spirocyclic oxindoles bearing a unique all-carbon quaternary stereogenic center via sulfa-Michael addition

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Publication details

The article was received on 09 Apr 2013, accepted on 15 May 2013 and first published on 16 May 2013


Article type: Communication
DOI: 10.1039/C3CC42587H
Citation: Chem. Commun., 2013,49, 6078-6080
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    Organocatalytic asymmetric desymmetrization: efficient construction of spirocyclic oxindoles bearing a unique all-carbon quaternary stereogenic center via sulfa-Michael addition

    L. Yao, K. Liu, H. Tao, G. Qiu, X. Zhou and C. Wang, Chem. Commun., 2013, 49, 6078
    DOI: 10.1039/C3CC42587H

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