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Issue 56, 2013
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Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

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Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

Graphical abstract: Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: structural insights and solvent effects

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Publication details

The article was received on 24 Mar 2013, accepted on 04 Jun 2013 and first published on 04 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC42125B
Citation: Chem. Commun., 2013,49, 6340-6342
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    Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

    D. J. Harding, W. Phonsri, P. Harding, I. A. Gass, K. S. Murray, B. Moubaraki, J. D. Cashion, L. Liu and S. G. Telfer, Chem. Commun., 2013, 49, 6340
    DOI: 10.1039/C3CC42125B

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