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Issue 55, 2013
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Cyclometalated metal–organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines

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Abstract

Metal–organic frameworks (MOFs) functionalized via Ir(I) cyclometalation are shown to be effective as heterogeneous catalysts for the allylic N-alkylation of various amines. The MOF catalysts are one of the first and most effective MOF-based heterogeneous organometallic catalysts for the direct formation of C–N bonds. In addition, these MOFs represent a rare, stable and reusable, class of reactive Ir catalysts.

Graphical abstract: Cyclometalated metal–organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines

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Publication details

The article was received on 23 Mar 2013, accepted on 25 May 2013 and first published on 29 May 2013


Article type: Communication
DOI: 10.1039/C3CC42119H
Citation: Chem. Commun., 2013,49, 6128-6130
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    Cyclometalated metal–organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines

    P. V. Dau and S. M. Cohen, Chem. Commun., 2013, 49, 6128
    DOI: 10.1039/C3CC42119H

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